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and amidine formation proceed through the common intermediate XXX formed by attachment of an amine group to the protonated carbonyl of any amide group (that in lactam monomer or the lactam end group in polymer or the amide groups in the repeat units of the polymer). Propagation involves cleavage of the C a bond (overall result is substitution N at carbonyl), while amidine formation involves loss of water from XXX (overall result is addition to carbonyl followed by dehydration). Amidine formation decreases the concentration of amine groups in the reaction system, and this leads to a slower rate of reaction. The water released during amidine formation can initiate polymerization (Sec. 7-3b), but at a slower rate. Furthermore, amidine groups react rapidly with acidic initiators to give relatively unreactive salts, and this limits the rate and degree of polymerization. Cationic polymerization is the only route to the polymerization of N-alkylated lactams. Both the hydrolytic and anionic routes require that a lactam have a hydrogen on the nitrogen. However, there are no commercial applications for N-alkylated polyamides, probably because their lack of hydrogen bonding results in lower melting points than for polyamides without an N-alkyl group.

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Hydrolytic polymerization of E-caprolactam to form nylon 6 (Sec. 2-8f) is carried out commercially in both batch and continuous processes by heating the monomer in the presence of 5 10% water to temperatures of 250 270 C for periods of 12 h to more than 24 h [Anton and Baird, 2002; Zimmerman, 1988]. Several equilibria are involved in the polymerization [Bertalan et al., 1984; Sekiguchi, 1984]. These are hydrolysis of the lactam to E-aminocaproic acid (Eq. 7-56), step polymerization of the amino acid with itself (Eq. 7-57), and initiation of ring-opening polymerization of lactam by the amino acid. The amino acid is

Id1 I c;

7-56 7-57

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the equivalent of XXIX in Eq. 7-54 (Z OH). The COOH group of the amino acid protonates the lactam to form XXVI followed by nucleophilic attack of amine on the protonated lactam. The propagation process follows in the same manner with nucleophilic attack of XXXII on protonated lactam to form XXXIII [R CH2 5 ]. Species XXXIII subsequently

Figures 5.4, 5.5, and 5.6 show examples of what an end user would see if they attempted to copy data to their BlackBerry and the respective policies were in place.

(n + 1)

7-58

It is common in the literature on robustness to define an estimator in terms of the function, as its behavior can be directly deduced from this function. There are two general approaches taken to this. We can:

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protonates lactam and propagation continues. The sequence is the same as in Eqs. 7-52 and 7-53 except for the propagating chain possessing a carboxyl end group instead of lactam end group. Hydrolytic polymerization is simply a special case of cationic polymerization. [The commercial processes often add E-aminocaproic acid or the 1 : 1 ammonium carboxylate salt from a diamine and diacid (Eq. 2-128) along with water. This is a faster route to initiation as it supplies amine and carboxyl groups at the very beginning instead of waiting for hydrolysis of the lactam to supply those groups.] The overall rate of conversion of E-caprolactam to polymer is higher than the polymerization rate of E-aminocaproic acid by more than an order of magnitude [Hermans et al., 1958, 1960]. Step polymerization of E-aminocaproic acid with itself (Eq. 7-57) accounts for only a few percent of the total polymerization of E-caprolactam. Ring-opening polymerization (Eq. 7-58) is the overwhelming route for polymer formation. Polymerization is acidcatalyzed as indicated by the observations that amines and sodium E-aminocaproate are poor initiators in the absence of water and the polymerization rate in the presence of water is rst-order in lactam and second-order in COOH end groups [Majury, 1958]. Although step polymerization of E-aminocaproic acid with itself is only a minor contribution to the overall conversion of lactam to polymer, it does determine the nal degree of polymerization at equilibrium since the polymer undergoes self-condensation. The nal

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